Respuesta :
Answer:
The correct answer is 1) 56 ml and 2) 0.314 M
Explanation:
1. The reaction taking place in the given case is,
HClO₃ + KOH ⇒ KClO₃ + H2O, the molarity of HClO₃ given is 0.100 M, the molarity of KOH given is 0.140 M and the volume of KOH given is 40 ml, there is a need to find the volume of HClO₃.
Therefore, the mole of HClO₃ = mole of KOH
= MHClO₃ × VHClO₃ = MKOH × VKOH
= 0.100 M × VHClO₃ = 0.140 M × 40 ml
VHClO₃ = 0.140 M × 40 ml/0.100 M
VHClO₃ = 56 ml.
2. The reaction taking place is,
2HNO₃ + Ba(OH)₂ ⇒ Ba(NO₃)₂ + 2H₂O
The volume of HNO₃ given is 25 ml, the molarity of Ba(OH)2 is 0.250 M, the volume of Ba(OH)2 is 15.7 ml, the n or the number of moles of HNO₃ is 2, and the n of Ba(OH)2 is 1, the concentration or M of HNO₃ is,
M₁V₁/n₁ = M₂V₂/n₂
M₁ × 25/ 2 = 0.25 × 15.7/1
M₁ or molarity of HNO₃ = 0.314 M
1. The volume of HClO₃ required to neutralize the KOH is 56.0 mL
2. The concentration of the original HNO₃ solution is 0.314 M
1.
First, we will write a balanced chemical equation for the reaction
The balanced chemical equation for the reaction is
HClO₃ + KOH → KClO₃ + H₂O
This means,
1 mole of HClO₃ is required to neutralize 1 mole of KOH
From the titration formula
[tex]\frac{C_{A}V_{A} }{C_{B}V_{B}} = \frac{n_{A}}{n_{B}}[/tex]
Where
[tex]C_{A}[/tex] is the concentration of acid
[tex]C_{B}[/tex] is the concentration of base
[tex]V_{A}[/tex] is the volume of acid
[tex]V_{B}[/tex] is the volume of base
[tex]n_{A}[/tex] is the mole ratio of acid
[tex]n_{B}[/tex] is the mole ratio of base
From the given information,
[tex]C_{A} = 0.100 \ M[/tex]
[tex]C_{B} = 0.140 \ M[/tex]
[tex]V_{B} = 40.0 \ mL[/tex]
From the balanced chemical equation
[tex]n_{A} = 1[/tex]
[tex]n_{B} =1[/tex]
Putting the values into the formula, we get
[tex]\frac{0.100 \times V_{A} }{0.140 \times 40.0} = \frac{1}{1}[/tex]
∴ [tex]0.100 \times V_{A} = 0.140 \times 40.0[/tex]
[tex]V_{A}=\frac{0.140\times 40.0}{0.100}[/tex]
[tex]V_{A}=\frac{5.60}{0.100}[/tex]
[tex]V_{A}=56.0 \ mL[/tex]
Hence, the volume of HClO₃ required to neutralize the KOH is 56.0 mL
2.
First, we will write the balanced chemical equation for the reaction
The balanced chemical equation for the reaction is
2HNO₃ + Ba(OH)₂ → Ba(NO₃)₂ + 2H₂O
This means, 2 mole of HNO₃ is required to neutralize 1 mole Ba(OH)₂
From the given information,
[tex]V_{A} = 25.0\ mL[/tex]
[tex]C_{B} = 0.250 \ M[/tex]
[tex]V_{B} = 15.7 \ mL[/tex]
From the balanced chemical equation
[tex]n_{A} = 2[/tex]
[tex]n_{B} =1[/tex]
Also, Using the titration formula
[tex]\frac{C_{A}V_{A} }{C_{B}V_{B}} = \frac{n_{A}}{n_{B}}[/tex]
We get
[tex]\frac{C_{A} \times 25.0 }{0.250 \times 15.7} = \frac{2}{1}[/tex]
Then,
[tex]C_{A} = \frac{2\times 0.250 \times 15.7} {1 \times 25.0}[/tex]
[tex]C_{A} =\frac{7.85}{25.0}[/tex]
[tex]C_{A} =0.314 \ M[/tex]
Hence, the concentration of the original HNO₃ solution is 0.314 M
Learn more here: https://brainly.com/question/16870772
