Consider an ideal gas enclosed in a 1.00 L container at an internal pressure of 10.0 atm.?
Consider an ideal gas enclosed in a 1.00 L container at an internal pressure of 10.0 atm.

Calculate the work, w, if the gas expands against a constant external pressure of 1.00 atm exerted by the surroundings to a final volume of 15.0 L.

Now calculate the work done if this process is carried out in two steps: Step 1: First let the gas expand against a constant external pressure of 5.00 atm to a volume of 3.00 L. Step 2: Now let the gas expand to 15.0 L against a constant external pressure of 1.00

Respuesta :

Answer:

  1. -1,42x10³ J
  2. -2,23x10³ J

Explanation:

When a gas expands it produce energy as work. The equation that explain this phenomenon is:

Work (w) = - External pressure × ΔV

In the first question. We have an external pressure of 1,00 atm and the ΔV is:

1,00 L - 15,0 L = 14 L

Thus, in this case work is:

w = - 1,00 atm × 14,0 L = -14,0 atm·L

The problem does not especify the units to solve this problem, for international system of units (SI) Joules is the correct unit for energy, so:

-14,0 atm·L ×(101,325 J / 1 atm·L) = -1,42x10³ J

In the second problem occurs the same principle but occurs in two steps. The work done in the first step is:

w = - 5,00 atm × (3,00 L - 1,00 L) = -10 atm·L ×(101,325 J / 1 atm·L) =

-1,01x10³ J

In second step:, the work is:

w = - 1,00 atm × (15,0 L - 3,00 L) = -12 atm·L ×(101,325 J / 1 atm·L) =

-1,22x10³ J

Thus, the work done in the process is:

w = -1,01x10³ J - 1,22x10³ J = -2,23 x10³ J

I hope it helps!

1) The workdone with the given values of external pressure and volume is; W = 14,185.5 J

2) Step 1; The work done with the given values of external pressure and volume is; W = 1013.25 J

Step 2; The work done with the given values of external pressure and volume is; W = 1418.55 J

1) We are given;

Formula for work done in isothermally irreversible expansion is;

W = -P_ext(V2 - V1)

We are given;

V1 = 1 L

V2 = 15 L

P_ext = 10 atm

Thus;

W = -10(15 - 1)

W = -140 atm•L

Converting to joules gives; W = -140 × 101.325

W = 14,185.5 J

2) Step 1;

We are given;

V1 = 1 L

V2 = 3 L

P_ext = 5 atm

Thus;

W = -5(3 - 1)

W = -10 atm.L

Converting to joules gives;

W = -10 × 101.325

W = -1013.25 J

Step 2;

We are given;

V1 = 1 L

V2 = 15 L

P_ext = 1 atm

Thus;

W = -1(15 - 1)

W = -14 atm.L

Converting to joules gives;

W = -14 × 101.325

W = 1418.55 J

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