C2H6O2 is infinitely miscible (soluble) in water. Ethylene glycol is a nonelectrolyte that is used as antifreeze. What is the lowest possible melting point for engine coolant that is 24.9 % (by mass) ethylene glycol?

Respuesta :

Answer:

- 7.4 ÂșC

Explanation:

The change in melting  temperature is given by:

ΔTm = Kf m

where kf is the molal freezing  point depresion  constant, and m is the molality.

The molality of a solution is calculated as

m = mol solute/ kg solvent

Since we have the % composition it is easy to calculate the molality :

In 100 g of solution we have  24.9 ethylene glycol

mol glycol = 24.9 g / 62.07 g/ mol = 0.40 mol

molality = 0.40 mol / 0.1 kg = 4 m

Km for water is 1.86 ÂșC/m,

therefore,  

ΔTm = Kf m = 1.86 ÂșC/m x 4 = 7.4 ÂșC

Tm = -7.4 ÂșC for a solution

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