Air is 78.1% nitrogen, 20.9% oxygen, and 0.934% argon by moles. What is the density of air at 22 °C and 760 torr? Assume ideal behavior.

Respuesta :

Answer:

The density of air at 22 °C and 760 torr is 1.195 KG/m³

Explanation:

The solution to the above  question is arrived t by considering the given variables and calculating the number of moles in a 1 m³ sample of air by plugging values into the universal gas equation  from which the number of moles of the constituent gases can be calculated by Dalton's law of partial pressure, then their masses and lastly the density of air is calculated using the formula, Density = mass/volume

The given variables are

Percentage Nitrogen = 78.1% by volume

Percentage oxygen = 20.9% by volume

Percentage argon = 0.934% by volume

The molar mass of nitrogen = 14.006g/mol

The molar mass of oxygen = 15.999g/mol

The molar mass of argon = 39.948 g/mol hence Considering a unit volume of air of one cubic meter (1m^3) we have

0.781 m³ of nitrogen, 0.209 m³ of oxygen and 0.00934 m³ of argon

The number of moles in 1 m³ of gas at 22 °C and 760 torr is given by

PV = nRT or n = [tex]\frac{PV}{RT}[/tex] = where 760 torr = 101325Pa we have n = [tex]\frac{(101325)(0.001)}{(8.314)(295.15)}[/tex] = 0.00413 mols per liter or 41.29 moles/m³

thus we have number of moles of nitrogen = 42.129 × 78.1% = 32.25 moles and the mass of nitrogen = 32.25×28.02 = 903.6 g

number of moles of oxygen= 42.129 × 20.1% = 8.63 moles and the mass of nitrogen = 8.63×32 = 276.16 g

number of moles of argon= 42.129 × 0.934% = 0.386 moles and the mass of nitrogen = 0.386×40 = 15.43 g

Therefore, mass of one cubic meter of air (1 m³), has a mass of

903.6 g + 276.16 g + 15.43 g = 1195.2 g or 1.195 KG Hence the density of air

is given by Density = [tex]\frac{mass}{volume}[/tex] =[tex]\frac{1.195 KG}{1 m^{3} }[/tex]  = 1.195 KG/m³

The density of air at 22 °C and 760 Torr is 1.19 g/L.

Air is 78.1% nitrogen, 20.9% oxygen, and 0.934% argon by moles. We will calculate the average molar mass of the air (M) as a weighted average of the molar masses of its constituents.

[tex]M = 78.1\% \times M(N_2) + 20.9\% \times M(O_2) + 0.934\% \times M(Ar)\\\\M = 78.1\% \times 28.00g/mol + 20.9\% \times 32.00g/mol + 0.934\% \times 39.95 g/mol = 28.93 g/mol[/tex]

Then, we will convert 22 °C to Kelvin using the following expression.

[tex]K = \° C + 273.15 = 22\° C + 273.15 = 295 K[/tex]

Assuming ideal behavior, we can calculate the density (ρ) of the air at 295 K (T) and 760 Torr (P) using the following expression.

[tex]\rho = \frac{P \times M }{R \times T} = \frac{760 Torr \times 28.93g/mol }{(62.4mmHg.L/mol.K) \times 295K} = 1.19 g/L[/tex]

where,

  • R: ideal gas constant

The density of air at 22 °C and 760 Torr is 1.19 g/L.

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