What is the [HPO42-]/[H2PO4-] ratio in an acetate buffer at pH 7.20? (The pKa for dihydrogenphosphate is 7.10.)

Respuesta :

Answer:

[tex]\frac{[HPO_4^{2-}]}{[H_2PO_4^{-}]}=1.26[/tex]

Explanation:

Considering the Henderson- Hasselbalch equation for the calculation of the pH of the buffer solution as:

pH=pKa+log[base]/[acid]

For the equilibrium buffer of dihydrogen phosphate, pKa = 7.10

pH = 7.20

[tex]pH=pKa+\log\frac{[base]}{[acid]}[/tex]

[tex]7.20=7.10+\log\frac{[HPO_4^{2-}]}{[H_2PO_4^{-}]}[/tex]

[tex]\log\frac{[HPO_4^{2-}]}{[H_2PO_4^{-}]}=0.10[/tex]

[tex]\frac{[HPO_4^{2-}]}{[H_2PO_4^{-}]}=1.26[/tex]

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