What mass of salt (NaCl) should you add to 1.46 L of water in an ice-cream maker to make a solution that freezes at -14.4 ∘C? Assume complete dissociation of the NaCl and a density of 1.00 g/mL for water and use Kf=1.86∘C/m.

Respuesta :

Answer:

We should add 330.2 grams of NaCl

Explanation:

Step 1: Data given

Volume of water = 1.46 L = 1460 mL

Density of water = 1.00 g/ mL

The solution freezes at -14.4 °C

Kf = 1.86 °C / m

Step 2: Calculate molality

ΔT = i*Kf*m

⇒ with ΔT = The change in temperature = -14.4 °C

⇒ with i = The van't Hoff factor for NaCl = 2

⇒ with Kf = 1.86°C/m

⇒ with m = the molality = TO BE DETERMINED

m = ΔT / (i*Kf)

m = 14.4 / (2*1.86)

m =3.87 molal

Step 3: Calculate moles of NaCl

Molality = moles Nacl / mass Water

3.87 molal = moles NaCl / 1.46 kg

Moles NaCl = 3.87 * 1.46

Moles NaCl = 5.65 moles

Step4: Calculate mass of NaCl

Mass NaCl = Moles NaCl * molar mass NaCl

Mass Nacl =5.65 moles * 58.44 g/mol

Mass NaCl =330.2 grams

We should add 330.2 grams of NaCl

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