For which set of crystallographic planes will a first-order diffraction peak occur at a diffraction angle of 44.53° for FCC nickel (Ni) when monochromatic radiation having a wavelength of 0.1542 nm is used? The atomic radius for Ni is 0.1246 nm.

Respuesta :

Answer:

The set of planes responsible for this diffraction peak is the [111] set.

Explanation:

We need to calculate the interplanar spacing, dₕₖₗ for nickel.

dₕₖₗ = nλ/2 sin θ

where θ = half of the diffraction angle = 44.53°/2 = 22.265°, n is the order of reflection = 1 and λ is the wavelength of the monochromatic radiation = 0.1542 nm.

dₕₖₗ = 1×0.1542/2sin 22.265°

dₕₖₗ = 0.2035 nm

But, interplanar spacing, dₕₖₗ is related to the plane (hkl), by the relation

√(h² + k² + l²) = a/dₕₖₗ

a is the lattice parameter.

Since Nickel has an FCC structure, a = 2R√2, R is given as 0.1242 nm

√(h² + k² + l²) = 2R√2/dₕₖₗ = (2×0.1246√2)/0.2035 = 1.732

(h² + k² + l²) = 1.732² = 3

The only 3 integers the values of h, k and l which fit properly into the equation is [111]

Therefore, the answer is [111].

Hope this Helps!!

  • When The set of planes responsible for this diffraction peak is the set.
  • Then We need to calculate the interplanar of the spacing, dₕₖₗ for a nickel.
  1. dₕₖₗ = nλ/2 sin θ  
  • Now where the θ = half of the diffraction angle is = 44.53°/2 = 22.265°, n is the order of the reflection = 1 and λ is the wavelength of the monochromatic radiation is = 0.1542 nm.  
  1. dₕₖₗ = 1×0.1542/2sin 22.265°
  2. dₕₖₗ = 0.2035 nm  
  • So that, interplanar spacing, dₕₖₗ is related to the plane (hkl), by the relation are  

                                 √(h² + k² + l²) = a/dₕₖₗ  

                   lattice parameterize is  

  • When the Nickel has an FCC structure, so that  = 2R√2, R is given as 0.1242 nm  

              =   √(h² + k² + l²) = 2R√2/dₕₖₗ = (2×0.1246√2)/0.2035 = 1.732  

                                   =    (h² + k² + l²) = 1.732² = 3

  • Then The only 3 integers are the values of h, k, and which is fit properly into the equation is 1

Learn more about:

https://brainly.com/question/16751596

Q&A Education