A 279.6 mL sample of an aqueous solution at 25°C contains 91.6 mg of an unknown nonelectrolyte compound. If the solution has an osmotic pressure of 8.44 torr, what is the molar mass (in g/mol) of the unknown compound?

Respuesta :

Answer:

The molar mass of the compound is 720.8 g/mol

Explanation:

Let's apply the colligative property of Osmotic pressure to solve this.

Formula is π = M . R . T

where π is pressure (atm)

M is molarity (mol/L)

R, Universal Constant Gases

T, Absolute T° ( T° in K = T° in C + 273)

Let's replace the data:

8.44 Torr = M . 0.082 L.atm/mol.K . 298K

As we have the pressure in Torr, we must convert to atm, to work properly.

8.44 Torr . 1 atm/ 760 Torr = 0.0111 atm

0.0111 atm = M . 0.082 L.atm/mol.K . 298K

0.0111 atm / (0.082 L.atm/mol.K . 298K) = M  → 4.54×10⁻⁴ mol/L

So molarity is the moles of solute (mass (g) / molar mass) / volume (L)

Let's convert the volume to L → 279.6 mL . 1L / 1000 mL = 0.2796 L

4.54×10⁻⁴ mol/L . 02796 L = 1.27×10⁻⁴ moles

This moles are represented by the 91.6 mg, so let's convert the mass of solute from mg to g

91.6 mg . 1 g / 1000 mg = 0.0916 g

Molar mass → g/mol → 0.0916 g / 1.27×10⁻⁴ moles → 720.8 g/mol

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