In a coffee-cup calorimeter experiment, 10.00 g of a soluble ionic compound was added to the calorimeter contained 75.0 g H2O initially at 23.2°C. The final temperature of the solution was 31.8°C. What was the change in enthalpy for the dissolution of this compound?

Respuesta :

Answer:

The enthalpy for dissolution is - 305.558 J/g

Solution:

Mass of the ionic compound, m = 10.00 g

Mass of water, m' = 75.0 g

Initial temperature, T = [tex]23.2^{\circ}C[/tex]

Final Temperature, T' = [tex]31.8^{\circ}C[/tex]

Now,

To calculate the change in enthalpy:

We know that the specific heat of water is 4.18 [tex]J/g^{\circ}C[/tex]

Total mass of the solution, M = m + m' = 10.00 + 75.0 = 85.0 g

Temperature, difference, [tex]\Delta T = T' - T = 31.8 - 23.2 = 8.6^{\circ}C[/tex]

Thus

The heat absorbed by the solution is given by:

[tex]Q = MC_{w}\Delta T = 85.0\times 4.18\times 8.6 = 3055.58\ J[/tex]

Enthalpy, [tex]\Delta H = -\frac{Q}{m} = - \frac{3055.58}{10} = - 305.558\ J/g[/tex]

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