Calculate the value of the equilibrium constant, Kc, for the reaction CuBr(s) + Br−(aq) ↽⇀ CuBr−2(aq) Kc= ? The solubility product constant, Ksp, for CuBr is 6.27×10−9 and the overall formation constant, Kf (????2), for CuBr2− is 8.0×105.

Respuesta :

Answer : The equilibrium constant for the reaction is [tex]5.0\times 10^{-3}[/tex]

Explanation :

The given equilibrium reaction is:

[tex]CuBr(s)+Br^-(aq)\rightleftharpoons [CuBr_2]^-(aq)[/tex]   [tex]K_c=?[/tex]

The dissociation reaction will be:

[tex]CuBr(s)\rightleftharpoons Cu^+(aq)+Br^-(aq)[/tex]   [tex]K_{sp}=6.27\times 10^{-9}[/tex]

The formation reaction will be:

[tex]Cu^+(aq)+2Br^-(aq)\rightleftharpoons [CuBr_2]^-(aq)[/tex]   [tex]K_f=8.0\times 10^{5}[/tex]

Thus, the value of equilibrium constant will be:

[tex]K_c=K_{sp}\times K_f[/tex]

Now put all the given values in this expression, we get:

[tex]K_c=(6.27\times 10^{-9})\times (8.0\times 10^{5})[/tex]

[tex]K_c=5.0\times 10^{-3}[/tex]

Therefore, the equilibrium constant for the reaction is [tex]5.0\times 10^{-3}[/tex]

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