a) If 2 kg of adipic acid and 4.5 kg of hexamethylene diamine are reacted to produce the polymer Nylon 6,6, estimate the amount of Nylon 6,6 produced. Assume 15% efficiency for the reaction.
b) What do you think is the difference between Nylon 6 and Nylon 6,6? Do you expect any differences properties between the two? Explain.

Respuesta :

a) mass of nylon 6,6 (15% yield) = 0.47 kg

b) Nylon 6 and Nylon 6,6 have different chemical structures so will have different physical properties.

Explanation:

a) First we need to calculate the number of moles of adipic acid and hemetylenediamine.

number of moles =  mass / molecular weight

number of moles of adipic acid = 2 / 146 = 0.0137 kmoles = 13.7 moles

number of moles of hemetylenediamine = 4.5 / 116 = 0.0389 kmoles = 38.9 moles

We see from the chemical reaction (see attached picture) that n moles of adipic acid will react with n moles of hemetylenediamine to produce the Nylon 6,6 and (2n-1) water moles.

From our data 13.7 moles of adipic acid will react with 13.7 moles of hemetylenediamine o produce the Nylon 6,6 and (2×13.7-1) water moles.

For a theoretical 100% yield mass of nylon 6,6 will be:

mass of nylon 6,6 = mass of reacted adipic acid + mass of reacted hemetylenediamine - mass of water

mass of reacted adipic acid = 2 kg

mass of reacted hemetylenediamine = number of moles × molecular weight

mass of reacted hemetylenediamine = 13.7 × 116 = 1589.2 g = 1.59 kg

mass of water = number of moles × molecular weight

mass of water = (2×13.7-1) × 18 = 475.5 g = 0.48 kg

mass of nylon 6,6 = 2 + 1.59 - 0.48 = 3.11 kg

Now if the yield of the reaction is 15% only 15% of the nylon 6,6 quantity will be produced:

mass of nylon 6,6 (15% yield) = (15 / 100) × 3.11 = 0.47 kg

b) You may find the chemical diagrams of Nylon 6 and Nylon 6,6 in the attached picture. They have different chemical structures. This will result in different physical properties.

density of nylon 6 = 1.084 g/mL

density of nylon 6,6 =  1.314 g/mL

melting point of nylon 6 = 220 °C

melting point of nylon 6,6 = 264 °C

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