Consider a compound that is 31.17% C, 6.54% H, and 62.29% O by mass. Assume that we have a 100 g sample of this compound. Also consider that the molecular formula mass of this compound is 231.2 amu. What are the subscripts in the actual molecular formula for this compound?

Respuesta :

Answer:  The molecular formula will be [tex]C_6H_{15}O_9[/tex]

Explanation:

If percentage are given and we are given total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C= 31.17 g

Mass of H = 6.54 g

Mass of O = 62.29 g

Step 1 : convert given masses into moles.

Moles of C =[tex]\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{31.17g}{12g/mole}=2.6moles[/tex]

Moles of H=[tex]\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{6.54g}{1g/mole}=6.54moles[/tex]

Moles of O =[tex]\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{62.29g}{16g/mole}=3.9moles[/tex]

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C= [tex]\frac{2.6}{2.6}=1[/tex]

For H = [tex]\frac{6.54}{2.6}=2.5[/tex]

For O =[tex]\frac{3.9}{2.6}=1.5[/tex]

The ratio of C: H: O= 1: 2.5: 1.5

Converting them into whole number ratios by multiplying by 2.

Hence the empirical formula is [tex]C_2H_5O_3[/tex]

The empirical weight of [tex]C_2H_5O_3[/tex] = 2(12)+5(1)+3(16)= 77 amu

The molecular weight = 231.2 amu

Now we have to calculate the molecular formula.

[tex]n=\frac{\text{Molecular weight }}{\text{Equivalent weight}}=\frac{231.2}{77}=3[/tex]

The molecular formula will be=[tex]3\times C_2H_5O_3=C_6H_{15}O_9[/tex]

The molecular formula will be [tex]C_6H_{15}O_9[/tex]

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