To standardize a solution of NaOH before using it in a titration of an unknown acid, you dissolve 2.48 grams of potassium hydrogen phthalate (KHP) into 100 mL of H2O. You then titrate the KHP with your sodium hydroxide solution and reach the endpoint after adding 20.4 mL of NaOH. What is the molarity of your sodium hydroxide solution?

Respuesta :

Answer: The molarity of NaOH solution is 1.03 M.

Explanation:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

Given mass of KHP = 2.48 g

Molar mass of KHP = 204.22 g/mol

Putting values in equation 1, we get:

[tex]\text{Moles of KHP}=\frac{2.48g}{204.22g/mol}=0.012mol[/tex]

The chemical reaction for the formation of chromium oxide follows the equation:

[tex]KHC_8H_4O_4(aq.)+NaOH\rightarrow KNaC_8H_4O_4(aq.)+H_2O(l)[/tex]

By Stoichiometry of the reaction:

1 mole of KHP reacts with 1 mole of NaOH.

So, 0.012 moles of KHP will react with = [tex]\frac{1}{1}\times 0.021=0.021mol[/tex] of NaOH.

To calculate the molarity of NaOH, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}[/tex]

We are given:

Moles of NaOH = 0.021 moles

Volume of solution = 20.4 mL  = 0.0204L      (Conversion factor:  1L = 1000 mL)

Putting values in above equation, we get:

[tex]\text{Molarity of NaOH }=\frac{0.021mol}{0.0204L}=1.03M[/tex]

Hence, the molarity of NaOH solution is 1.03 M.

Answer:

The molarity of NaOH solution is 1.03 M.

Explanation:

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