Consider the reaction: 3A + B + 2 C -> D + E where rate = k[A]2 [C]2 .A reaction was performed where [B]o = [C]o = 0.600 M and [A]o = 2.20 x 10-5 M. A plot of 1/[A] vs time (min) gave a plot with a straight line relationship and after 7.00 min, [A] = 2.4 x 10-6 M. What was the initial rate of the reaction described above?

Respuesta :

Explanation:

As the given reaction is [tex]3A + B + 2C \rightarrow D + E[/tex]

Also,  rate = k[tex][A]^{2}[C]^{2}[/tex]

So, rate is zero order with respect to B and it is second order with respect to both A and C.

It is given that [A] = [tex]2.4 \times 10^{-6} M[/tex] and [tex][A]_{0} = [tex]2.20 \times 10^{-5} M[/tex]

For second order rate law, equation is as follows.

        [tex]\frac{1}{[A]} = \frac{1}{[A]_{0}} + kt[/tex]

        [tex]\frac{1}{2.4 \times 10^{-6}} = \frac{1}{2.20 \times 10^{-5}} + k \times 7 min[/tex]

                    k = [tex]0.412 \times 10^{5} M^{-1} sec^{-1}[/tex]

As, the initial rate = k [tex][A]^{2}_{o} [C]^{2}_{o}[/tex]

                              = 0.412 \times 10^{5} M^{-1} sec^{-1} \times (2.20 \times 10^{-5} M)^{2} \times (0.6 M)^{2}[/tex]

                               = [tex]0.717 \times 10^{-5} M^{3} sec^{-1}[/tex]

Thus, we can conclude that the initial rate of the reaction described above is [tex]0.717 \times 10^{-5} M^{3} sec^{-1}[/tex].

Q&A Education