For each of the following pairs of solids, determine which solid has the smallest molar solubility.
a. FeC2O4, Ksp = 4.0 x 10-11 or Cu(IO4)2, Ksp = 1.4 x 10-7
b. Ag2CO3, Ksp = 8.1 x 10-12 or Mn(OH)2, Ksp = 2 x 10-13