Which of the following will not produce a buffered solution? Question 1 options: 1) 100 mL of 0.1 M Na2CO3 and 50 mL of 0.1 M HCl 2) 100 mL of 0.1 M NaHCO3 and 25 mL of 0.2 M HCl 3) 100 mL of 0.1 M Na2CO3 and 75 mL of 0.2 M HCl 4) 50 mL of 0.2 M Na2CO3 and 5 mL of 1.0 M HCl 5) 100 mL of 0.1 M Na2CO3 and 50 mL of 0.1 M NaOH